The village of Kapitan Dimitrievo is situated in southern Bulgarian, Peshtera municipality, Pazardzhik region, some 100 kilometres southeast of the capital Sofia. It is situated 15km from district center town of Pazardjik at road Pazardjik - Velingrad. The village is surrounded by hills (called from local inhabitants "Chalove"). The small river of Pishmanka pass the village center. An ancient sanctuary dated back to the Neolithic was discovered near the village of Kapitan Dimitrievo.